Samiksha Jaiswal (Editor)

Cobalt(II,III) oxide

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Formula
  
Co3O4

Melting point
  
895 °C

Boiling point
  
900 °C

Molar mass
  
240.8 g/mol

Density
  
6.11 g/cm³

Appearance
  
black solid

Cobalt(II,III) oxide httpsuploadwikimediaorgwikipediacommonsthu

Cobalt(II,III) oxide is inorganic compound with the formula Co3O4. It is one of two well characterized cobalt oxides. It is a black antiferromagnetic solid. As a mixed valence compound, its formula is sometimes written as CoIICoIII2O4 and sometimes as CoO•Co2O3.

Contents

Structure

Co3O4 adopts the normal spinel structure, with Co2+ ions in tetrahedral interstices and Co3+ ions in the octahedral interstices of the cubic close-packed lattice of oxide anions.

Synthesis

Cobalt(II) oxide, CoO, converts to Co3O4 if heated to around 600-700 °C in air. Above 900 °C, CoO is stable. These reaction are described by the following equilibrium:

2 Co3O4 ⇌ 6 CoO + O2

Research

This inorganic compound is currently utilized in the process of artificial photosynthesis.

Safety

Cobalt compounds are potentially poisonous in large amounts.

References

Cobalt(II,III) oxide Wikipedia