Kalpana Kalpana (Editor)

Caesium hexafluorocobaltate(IV)

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Caesium hexafluorocobaltate(IV) is a rare example of cobalt(IV) complexs with the chemical formula Cs
2
CoF
6
. It can be synthesized by the reaction of Cs
3
[(CoCl
4
)Cl]
and fluorine.

It has cubic K2PtCl6 structure, with the lattice constant a = 8.91 Å, and the length of Co-F bond is 1.73 Å. Its ferromagnetic is complex and the ground state of Co(IV) is 2T2.

References

Caesium hexafluorocobaltate(IV) Wikipedia