Rahul Sharma (Editor)

Arsenolite

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Category
  
Oxide mineral

Strunz classification
  
4.CB.50

Space group
  
Fd3m

Formula (repeating unit)
  
As4O6

Crystal system
  
Cubic

Arsenolite

Crystal class
  
Hexoctahedral (m3m) H-M symbol: (4/m 3 2/m)

Arsenolite is an arsenic mineral, chemical formula As4O6. It is formed as an oxidation product of arsenic sulfides. Commonly found as small octahedra it is white, but impurities of realgar or orpiment may give it a pink or yellow hue. It can be associated with its dimorph claudetite (a monoclinic form of As2O3) as well as realgar (As4S4), orpiment (As2S3) and erythrite, Co3(AsO4)2ยท8H2O.

Arsenolite belongs to the minerals which are highly toxic.

Occurrence

It was first described in 1854 for an occurrence in the St Andreasberg District, Harz Mountains, Lower Saxony, Germany.

It occurs by the oxidation of arsenic-bearing sulfides in hydrothermal veins. It also occurs as a result of mine or coal seam fires.

References

Arsenolite Wikipedia