Harman Patil (Editor)

Anzaite (Ce)

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Category
  
Oxide mineral

Crystal system
  
Monoclinic

Formula (repeating unit)
  
Ce4FeTi6O18(OH)2

Space group
  
C2/m

Crystal class
  
Prismatic (2/m) (same H-M symbol)

Unit cell
  
a = 5.29, b = 14.58 c = 5.23 [Å]; β = 97.23° (approximated); Z = 1

Anzaite-(Ce) is a rare earth element (REE) oxide mineral with the formula Ce4Fe2+Ti6O18(OH)2. An example of chemically related mineral is lucasite-(Ce), although it contains no iron. Cerium in anzaite-(Ce) is mainly substituted by neodymium, lanthanum, calcium and praseodymium. Titanium is substituted by niobium. Trace elements include thorium. The mineral is monoclinic, space group C2/m. Anzaite-(Ce) is hydrothermal mineral found in a carbonatite from the mineralogically-prolific Kola Peninsula. The mineral name honors Anatoly N. Zaitsev, who is known for studies of carbonatites and REE.

Contents

Occurrence and association

Parent rocks for anzaite-(Ce) are silicocarbonatites of the Afrikanda alkali-ultramafic massif. These rocks underwent hydrothermal reworking, that beside anzaite-(Ce) produced also calcite, clinochlore, hibschite and titanite in expense of primary minerals.

Crystal structure

The crystal structure of anzaite-(Ce) characterizes in:

  • the presence of layers with REE (square antiprismatic coordination) and Fe (octahedral)
  • the presence of layers with Ti with coordination numbers 5 and 6
  • disorder of Fe, VTi and two of four present anion sites
  • The disordered sites are located on the (010) planes, separated by ordered domains containing REE, VITi (octahedral) and two oxide-anion sites.

    References

    Anzaite-(Ce) Wikipedia