Neha Patil (Editor)

15 Crown 5

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Density  1.11 g/cm³
Appearance  Clear, colorless liquid
15-Crown-5 wwwsigmaaldrichcomcontentdamsigmaaldrichstr

15-Crown-5 is a crown ether with the formula (C2H4O)5. It is a cyclic pentamer of ethylene oxide that forms complex with various cations, including sodium (Na+) and potassium (K+), however, it is complementary to Na+ and thus has a higher selectivity for Na+ ions.

15-Crown-5 Benzo15crown5 98 SigmaAldrich

Properties

15-Crown-5 15Crown5 C10H20O5 ChemSpider

Analogous to 18-crown-6, 15-crown-5 binds to sodium ions. Thus, when treated with this complexing agent, sodium salts often become soluble in organic solvents.

15-Crown-5 15Crown5 Wikiwand

First-row transition metal dications fit snugly inside the cavity of 15-crown-5. They are too small to be included in 18-crown-6. The binding of transition metal cations results in multiple hydrogen-bonded interactions from both equatorial and axial aqua ligands, such that highly crystalline solid-state supramolecular polymers can be isolated. Metal salts isolated in this form include Co(ClO4)2, Ni(ClO4)2, Cu(ClO4)2, and Zn(ClO4)2. Seven coordinate species are most common for transition metal ions complexes of 15-crown-5, with the crown ether occupying the equatorial plane, along with 2 axial aqua ligands.

15-Crown-5 15Crown5 Exporter from Pune

15-crown-5 have also been used to isolate salts of oxonium ions. For example, from a solution of tetrachloroauric acid, the oxonium ion [H7O3]+ has been isolated as the salt [(H7O3)(15-crown-5)2][AuCl4]. Neutron diffraction studies revealed a sandwich structure, which shows a chain of water with remarkably long O-H bond (1.12 Å) in the acidic proton, but with a very short OH•••O distance (1.32 Å).

A derivative of 15-crown-5, benzo-15-crown-5, has been used to produce anionic complexes of carbido ligands as their [K(benzo-15-crown-5)2]+ salts:

(Ar2N)3MoCH + KCH2Ph + 2 15-crown-5 → [K(15-crown-5)2]+[(Ar2N)3MoC] + CH3Ph
15-Crown-5

References

15-Crown-5 Wikipedia


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